The Gibbs Phase Rule That there is a definite relationship in a system between the number of degrees of freedom, the number of components and the number of phases present was first established by J. Willard Gibbs in 1876. This relation, known as the phase rule, is a principle of the widest generality, and its validity is in no way dependent on any concepts of the atomic or molecular constitution. Credit is due to Ostwald, Roozeboom, Van't Hoff, and others for showing how this generalization can be 'utilized in the study of problems in heterogeneous equilibrium. To arrive at a formulation of the phase rule, consider in general a system of C components in which P phases are present. The problem now is to determine the total number of variables upon which such a system depends. First, the state of the system will depend upon the pressure and the temperature. Again, in order to define the composition of each phase, it is necessary to specify the concentration of (C-1) constitu...
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